Tetrakis(di-4-pyridylsulfane)dinitratocopper(II)
نویسندگان
چکیده
In the title complex, [Cu(NO(3))(2)(C(10)H(8)N(2)S)(4)], the Cu(II) atom (site symmetry ) is coordinated by two monodentate nitrate ions and two monodentate di-4-pyridylsulfane ligands, resulting in a slightly distorted trans-arranged CuO(2)N(4) octa-hedral geometry. Intra-molecular C-H⋯O hydrogen bonds are present. In the crystal, adjacent mol-ecules are linked via C-H⋯N hydrogen bonds into chains parallel to the a axis. Inter-molecular C-H⋯O inter-actions also occur.
منابع مشابه
Tetrakis(μ-2-phenylacetato-κ2 O:O′)bis{[4-(dimethylamino)pyridine-κN 1]cobalt(II)}
The title compound, [Co2(C8H7O2)4(C7H10N2)2], crystallizes as a centrosymmetric dimer containing two Co(II) atoms bridged by four bidentate phenyl-acetate ligands in syn-syn bridging modes. Each Co(II) atom is five-coordinated by four O atoms from four different carboxyl-ate ligands and the ring N atom of a 4-(di-methyl-amino)-pyridine unit, generating a distorted square-pyramidal geometry in w...
متن کاملTetrakis(μ-naphthalene-1-acetato-κ2 O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)O(2))(4)(C(3)H(7)NO)(2)], contains two independent centrosymmetric dinuclear copper(II) complexes. The central paddle-wheel units are formed by four bridging bidentate naphthalene-1-acetate ligands with two dimethyl-formamide ligands in the axial positions. The unique Cu(II) ions have slightly distorted square-pyramidal coordination geo...
متن کاملTetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate
The tetra-nuclear title complex, [Cu(4)(C(7)H(4)O(3))(2)(OH)(2)(C(10)H(8)N(2))(4)](NO(3))(2)·4H(2)O, has a crystallographically imposed centre of symmetry. The Cu(II) atoms display a distorted square-pyramidal coordination geometry and are linked by two μ(2)-phenolate O atoms from the salicylate ligands and two μ(3)-hydroxo groups, forming a Cu(4)O(4) core that adopts a 'stepped-cubane' geometr...
متن کاملTetrakis(2,2′-bipyridyl)dichloridodi-μ3-hydroxido-di-μ2-hydroxido-tetracopper(II) dinitrate hexahydrate
The tetra-nuclear copper(II) title complex, [Cu(4)Cl(2)(OH)(4)(C(10)H(8)N(2))(4)](NO(3))(2)·6H(2)O, has a crystallographically imposed centre of symmetry. The metal atoms display a distorted tetragonal-pyramidal coordination geometry, and are linked by two μ(2)- and two μ(3)-hydroxo groups, assuming a chair-like conformation for the Cu(4)O(2) core. In the crystal, the complex mol-ecules are lin...
متن کاملDi-μ4-succinato-tetrakis[aquaphenanthrolinecopper(II)] tetranitrate tetrahydrate
In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetra-cation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N'-bidentate phenanthroline mol-ecule, two O-monodentate bis-bridging succinate dianions and a water mol-ecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometr...
متن کامل